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Catalyst Control over Regio- and Enantioselectivity in Baeyer–Villiger Oxidations of Functionalized Ketones

[Image: see text] We report a peptide-based catalyst that can strongly influence the regio- and enantioselectivity of the Baeyer–Villiger (BV) oxidation of cyclic ketones bearing amide, urea, or sulfonamide functional groups. Both types of selectivity are thought to arise from a catalyst–substrate h...

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Detalles Bibliográficos
Autores principales:	Romney, David K., Colvin, Sean M., Miller, Scott J.
Formato:	Online Artículo Texto
Lenguaje:	English
Publicado:	American Chemical Society 2014
Acceso en línea:	https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4195385/ https://www.ncbi.nlm.nih.gov/pubmed/25250713 http://dx.doi.org/10.1021/ja508757g

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