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Catalytic Asymmetric α-Iminol Rearrangement: New Chiral Platforms
[Image: see text] A series of 19 different asymmetric catalysts were screened in an effort to identify the first chiral catalyst for the rearrangement of α-hydroxy imines to α-amino ketones involving a 1,2-carbon shift. Although aluminate complexes of VAPOL, VANOL, and 7,7′-(t)Bu(2)VANOL were quite...
| Autores principales: | , , , |
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| Formato: | Online Artículo Texto |
| Lenguaje: | English |
| Publicado: |
American Chemical
Society
2014
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| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4195388/ https://www.ncbi.nlm.nih.gov/pubmed/25247674 http://dx.doi.org/10.1021/ja5065685 |