Useful Method for the Preparation of Low-Coordinate Nickel(I) Complexes via Transformations of the Ni(I) Bis(amido) Complex K{Ni[N(SiMe(3))(2,6-(i)Pr(2)-C(6)H(3))](2)}

[Image: see text] A convenient method of preparing two- and three-coordinate Ni(I) complexes of the form L–Ni(I)–X (L = P(t)Bu(3), P(i)Pr(3), DPPE, NHC; X = −N(SiMe(3))(2,6-(i)Pr-C(6)H(3)), −O(2,6-(t)Bu(2)-4-Me-C(6)H(2))) is reported. Protonation of the easily prepared anionic Ni(I) bis(amido) compl...

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Detalles Bibliográficos
Autores principales: Lipschutz, Michael I., Tilley, T. Don
Formato: Online Artículo Texto
Lenguaje:English
Publicado: American Chemical Society 2014
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4195509/
https://www.ncbi.nlm.nih.gov/pubmed/25328273
http://dx.doi.org/10.1021/om500849u

Internet

https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4195509/
https://www.ncbi.nlm.nih.gov/pubmed/25328273
http://dx.doi.org/10.1021/om500849u

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