Alkenes as Chelating Groups in Diastereoselective Additions of Organometallics to Ketones

[Image: see text] Alkenes have been discovered to be chelating groups to Zn(II), enforcing highly stereoselective additions of organozincs to β,γ-unsaturated ketones. (1)H NMR studies and DFT calculations provide support for this surprising chelation mode. The results expand the range of coordinatin...

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Detalles Bibliográficos
Autores principales: Raffier, Ludovic, Gutierrez, Osvaldo, Stanton, Gretchen R., Kozlowski, Marisa C., Walsh, Patrick J.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: American Chemical Society 2014
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4195513/
https://www.ncbi.nlm.nih.gov/pubmed/25328269
http://dx.doi.org/10.1021/om5007006

Internet

https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4195513/
https://www.ncbi.nlm.nih.gov/pubmed/25328269
http://dx.doi.org/10.1021/om5007006

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