Mechanistic Investigations of Cu-Catalyzed Fluorination of Diaryliodonium Salts: Elaborating the Cu(I)/Cu(III) Manifold in Copper Catalysis

[Image: see text] A combination of experimental and density functional theory (DFT) investigations suggests that the Cu-catalyzed fluorination of unsymmetrical diaryliodonium salts with general structure [Mes(Ar)I](+) in N,N′-dimethylformamide proceeds through a Cu(I)/Cu(III) catalytic cycle. A low...

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Detalles Bibliográficos
Autores principales: Ichiishi, Naoko, Canty, Allan J., Yates, Brian F., Sanford, Melanie S.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: American Chemical Society 2014
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4195515/
https://www.ncbi.nlm.nih.gov/pubmed/25328272
http://dx.doi.org/10.1021/om5007903

Internet

https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4195515/
https://www.ncbi.nlm.nih.gov/pubmed/25328272
http://dx.doi.org/10.1021/om5007903

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