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Mechanistic Investigations of Cu-Catalyzed Fluorination of Diaryliodonium Salts: Elaborating the Cu(I)/Cu(III) Manifold in Copper Catalysis
[Image: see text] A combination of experimental and density functional theory (DFT) investigations suggests that the Cu-catalyzed fluorination of unsymmetrical diaryliodonium salts with general structure [Mes(Ar)I](+) in N,N′-dimethylformamide proceeds through a Cu(I)/Cu(III) catalytic cycle. A low...
| Autores principales: | , , , |
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| Formato: | Online Artículo Texto |
| Lenguaje: | English |
| Publicado: |
American
Chemical Society
2014
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| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4195515/ https://www.ncbi.nlm.nih.gov/pubmed/25328272 http://dx.doi.org/10.1021/om5007903 |