A remarkable cyclization of TADDOL-bisthioacetate under oxidative conditions

ABSTRACT: Attempted oxidation of a TADDOL-derived bisthioacetate resulted in a rather unexpected and remarkable cyclization and deprotection reaction, giving a thiolane-1,1-dioxide as the main product. Systematic in situ ESI-HRMS studies revealed a bicyclic, highly acid labile key intermediate of th...

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Detalles Bibliográficos
Autores principales: Waser, Mario, Haunschmidt, Manuela, Himmelsbach, Markus
Formato: Online Artículo Texto
Lenguaje:English
Publicado: Springer Vienna 2010
Materias:
Original Paper
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4202191/
https://www.ncbi.nlm.nih.gov/pubmed/25339780
http://dx.doi.org/10.1007/s00706-010-0410-5

Internet

https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4202191/
https://www.ncbi.nlm.nih.gov/pubmed/25339780
http://dx.doi.org/10.1007/s00706-010-0410-5

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