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A Group of Sequence-Related Sphingomonad Enzymes Catalyzes Cleavage of β-Aryl Ether Linkages in Lignin β-Guaiacyl and β-Syringyl Ether Dimers

[Image: see text] Lignin biosynthesis occurs via radical coupling of guaiacyl and syringyl hydroxycinnamyl alcohol monomers (i.e., “monolignols”) through chemical condensation with the growing lignin polymer. With each chain-extension step, monolignols invariably couple at their β-positions, generat...

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Detalles Bibliográficos
Autores principales: Gall, Daniel L., Ralph, John, Donohue, Timothy J., Noguera, Daniel R.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: American Chemical Society 2014
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4207535/
https://www.ncbi.nlm.nih.gov/pubmed/25232892
http://dx.doi.org/10.1021/es503886d