syn-1,2-Carboboration of Alkynes with Borenium Cations

The reaction of 8-(trimethylsiloxy)quinoline (QOTMS) with BCl(3) and (aryl)BCl(2) forms QOBCl(2) and QOBCl(aryl). The subsequent addition of stoichiometric AlCl(3) follows one of two paths, dependent on the steric demands of the QO ligand and the electrophilicity of the resulting borenium cation. Th...

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Detalles Bibliográficos
Autores principales: Cade, Ian A, Ingleson, Michael J
Formato: Online Artículo Texto
Lenguaje:English
Publicado: WILEY-VCH Verlag 2014
Materias:
Full Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4209141/
https://www.ncbi.nlm.nih.gov/pubmed/25138585
http://dx.doi.org/10.1002/chem.201403614

Internet

https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4209141/
https://www.ncbi.nlm.nih.gov/pubmed/25138585
http://dx.doi.org/10.1002/chem.201403614

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