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syn-1,2-Carboboration of Alkynes with Borenium Cations
The reaction of 8-(trimethylsiloxy)quinoline (QOTMS) with BCl(3) and (aryl)BCl(2) forms QOBCl(2) and QOBCl(aryl). The subsequent addition of stoichiometric AlCl(3) follows one of two paths, dependent on the steric demands of the QO ligand and the electrophilicity of the resulting borenium cation. Th...
| Autores principales: | , |
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| Formato: | Online Artículo Texto |
| Lenguaje: | English |
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WILEY-VCH Verlag
2014
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| Materias: | |
| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4209141/ https://www.ncbi.nlm.nih.gov/pubmed/25138585 http://dx.doi.org/10.1002/chem.201403614 |