Anisotropic Covalency Contributions to Superexchange Pathways in Type One Copper Active Sites

[Image: see text] Type one (T1) Cu sites deliver electrons to catalytic Cu active sites: the mononuclear type two (T2) Cu site in nitrite reductases (NiRs) and the trinuclear Cu cluster in the multicopper oxidases (MCOs). The T1 Cu and the remote catalytic sites are connected via a Cys-His intramole...

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Detalles Bibliográficos
Autores principales: Hadt, Ryan G., Gorelsky, Serge I., Solomon, Edward I.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: American Chemical Society 2014
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4210080/
https://www.ncbi.nlm.nih.gov/pubmed/25310460
http://dx.doi.org/10.1021/ja508361h

Internet

https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4210080/
https://www.ncbi.nlm.nih.gov/pubmed/25310460
http://dx.doi.org/10.1021/ja508361h

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