Toward Models for the Full Oxygen-Evolving Complex of Photosystem II by Ligand Coordination To Lower the Symmetry of the Mn(3)CaO(4) Cubane: Demonstration That Electronic Effects Facilitate Binding of a Fifth Metal

[Image: see text] Synthetic model compounds have been targeted to benchmark and better understand the electronic structure, geometry, spectroscopy, and reactivity of the oxygen-evolving complex (OEC) of photosystem II, a low-symmetry Mn(4)CaO(n) cluster. Herein, low-symmetry Mn(IV)(3)GdO(4) and Mn(I...

Descripción completa

Detalles Bibliográficos
Autores principales: Kanady, Jacob S., Lin, Po-Heng, Carsch, Kurtis M., Nielsen, Robert J., Takase, Michael K., Goddard, William A., Agapie, Theodor
Formato: Online Artículo Texto
Lenguaje:English
Publicado: American Chemical Society 2014
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4210109/
https://www.ncbi.nlm.nih.gov/pubmed/25241826
http://dx.doi.org/10.1021/ja508160x

Internet

https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4210109/
https://www.ncbi.nlm.nih.gov/pubmed/25241826
http://dx.doi.org/10.1021/ja508160x

Ejemplares similares