Cargando…

Nickel-Catalyzed Asymmetric Reductive Cross-Coupling Between Vinyl and Benzyl Electrophiles

[Image: see text] A Ni-catalyzed asymmetric reductive cross-coupling between vinyl bromides and benzyl chlorides has been developed. This method provides direct access to enantioenriched products bearing aryl-substituted tertiary allylic stereogenic centers from simple, stable starting materials. A...

Descripción completa

Detalles Bibliográficos
Autores principales: Cherney, Alan H., Reisman, Sarah E.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: American Chemical Society 2014
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4210114/
https://www.ncbi.nlm.nih.gov/pubmed/25245492
http://dx.doi.org/10.1021/ja508067c