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Hydrogen Production Catalyzed by Bidirectional, Biomimetic Models of the [FeFe]-Hydrogenase Active Site
[Image: see text] Active site mimics of [FeFe]-hydrogenase are shown to be bidirectional catalysts, producing H(2) upon treatment with protons and reducing equivalents. This reactivity complements the previously reported oxidation of H(2) by these same catalysts in the presence of oxidants. The comp...
Autores principales: | , , , |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
American
Chemical Society
2014
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Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4210170/ https://www.ncbi.nlm.nih.gov/pubmed/25364093 http://dx.doi.org/10.1021/om5004013 |