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Pyranopterin Dithiolene Distortions Relevant to Electron Transfer in Xanthine Oxidase/Dehydrogenase

[Image: see text] The reducing substrates 4-thiolumazine and 2,4-dithiolumazine have been used to form Mo(IV)-product complexes with xanthine oxidase (XO) and xanthine dehydrogenase. These Mo(IV)-product complexes display an intense metal-to-ligand charge-transfer (MLCT) band in the near-infrared re...

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Detalles Bibliográficos
Autores principales: Dong, Chao, Yang, Jing, Leimkühler, Silke, Kirk, Martin L.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: American Chemical Society 2014
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4215880/
https://www.ncbi.nlm.nih.gov/pubmed/24979205
http://dx.doi.org/10.1021/ic500873y