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Superoxide chemistry revisited: synthesis of tetrachloro-substituted methylenenortricyclenes
An unexpected reactivity of the superoxide ion leading to the synthesis of tetrachloroaryl/vinyl-substituted nortricyclenes through its dual mode of action has been reported. KO(2) was found to be superior and the only reagent to perform this kind of reaction over other conventional bases. Addition...
Autores principales: | , |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
Beilstein-Institut
2014
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4222393/ https://www.ncbi.nlm.nih.gov/pubmed/25383124 http://dx.doi.org/10.3762/bjoc.10.264 |