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Superoxide chemistry revisited: synthesis of tetrachloro-substituted methylenenortricyclenes

An unexpected reactivity of the superoxide ion leading to the synthesis of tetrachloroaryl/vinyl-substituted nortricyclenes through its dual mode of action has been reported. KO(2) was found to be superior and the only reagent to perform this kind of reaction over other conventional bases. Addition...

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Detalles Bibliográficos
Autores principales: Budanur, Basavaraj M, Khan, Faiz Ahmed
Formato: Online Artículo Texto
Lenguaje:English
Publicado: Beilstein-Institut 2014
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4222393/
https://www.ncbi.nlm.nih.gov/pubmed/25383124
http://dx.doi.org/10.3762/bjoc.10.264