Cargando…

Metal-Free Reductive Cleavage of C–N and S–N Bonds by Photoactivated Electron Transfer from a Neutral Organic Donor**

A photoactivated neutral organic super electron donor cleaves challenging arenesulfonamides derived from dialkylamines at room temperature. It also cleaves a) ArC–NR and b) ArN–C bonds. This study also highlights the assistance given to these cleavage reactions by the groups attached to N in (a) and...

Descripción completa

Detalles Bibliográficos
Autores principales: O'Sullivan, Steven, Doni, Eswararao, Tuttle, Tell, Murphy, John A
Formato: Online Artículo Texto
Lenguaje:English
Publicado: WILEY-VCH Verlag 2014
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4227565/
https://www.ncbi.nlm.nih.gov/pubmed/24311295
http://dx.doi.org/10.1002/anie.201306543