Metal-Free Reductive Cleavage of C–N and S–N Bonds by Photoactivated Electron Transfer from a Neutral Organic Donor**

A photoactivated neutral organic super electron donor cleaves challenging arenesulfonamides derived from dialkylamines at room temperature. It also cleaves a) ArC–NR and b) ArN–C bonds. This study also highlights the assistance given to these cleavage reactions by the groups attached to N in (a) and...

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Autores principales: O'Sullivan, Steven, Doni, Eswararao, Tuttle, Tell, Murphy, John A
Formato: Online Artículo Texto
Lenguaje:English
Publicado: WILEY-VCH Verlag 2014
Materias:
Communications
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4227565/
https://www.ncbi.nlm.nih.gov/pubmed/24311295
http://dx.doi.org/10.1002/anie.201306543
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author O'Sullivan, Steven
Doni, Eswararao
Tuttle, Tell
Murphy, John A
author_facet O'Sullivan, Steven
Doni, Eswararao
Tuttle, Tell
Murphy, John A
author_sort O'Sullivan, Steven
collection PubMed
description A photoactivated neutral organic super electron donor cleaves challenging arenesulfonamides derived from dialkylamines at room temperature. It also cleaves a) ArC–NR and b) ArN–C bonds. This study also highlights the assistance given to these cleavage reactions by the groups attached to N in (a) and to C in (b), by lowering LUMO energies and by stabilizing the products of fragmentation.
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spelling pubmed-42275652014-12-22 Metal-Free Reductive Cleavage of C–N and S–N Bonds by Photoactivated Electron Transfer from a Neutral Organic Donor** O'Sullivan, Steven Doni, Eswararao Tuttle, Tell Murphy, John A Angew Chem Int Ed Engl Communications A photoactivated neutral organic super electron donor cleaves challenging arenesulfonamides derived from dialkylamines at room temperature. It also cleaves a) ArC–NR and b) ArN–C bonds. This study also highlights the assistance given to these cleavage reactions by the groups attached to N in (a) and to C in (b), by lowering LUMO energies and by stabilizing the products of fragmentation. WILEY-VCH Verlag 2014-01-07 2013-12-06 /pmc/articles/PMC4227565/ /pubmed/24311295 http://dx.doi.org/10.1002/anie.201306543 Text en © 2013 The Authors. Published by Wiley-VCH Verlag GmbH & Co. KGaA. http://creativecommons.org/licenses/by/3.0/ This is an open access article under the terms of the Creative Commons Attribution License, which permits use, distribution and reproduction in any medium, provided the original work is properly cited.
spellingShingle Communications
O'Sullivan, Steven
Doni, Eswararao
Tuttle, Tell
Murphy, John A
Metal-Free Reductive Cleavage of C–N and S–N Bonds by Photoactivated Electron Transfer from a Neutral Organic Donor**
title Metal-Free Reductive Cleavage of C–N and S–N Bonds by Photoactivated Electron Transfer from a Neutral Organic Donor**
title_full Metal-Free Reductive Cleavage of C–N and S–N Bonds by Photoactivated Electron Transfer from a Neutral Organic Donor**
title_fullStr Metal-Free Reductive Cleavage of C–N and S–N Bonds by Photoactivated Electron Transfer from a Neutral Organic Donor**
title_full_unstemmed Metal-Free Reductive Cleavage of C–N and S–N Bonds by Photoactivated Electron Transfer from a Neutral Organic Donor**
title_short Metal-Free Reductive Cleavage of C–N and S–N Bonds by Photoactivated Electron Transfer from a Neutral Organic Donor**
title_sort metal-free reductive cleavage of c–n and s–n bonds by photoactivated electron transfer from a neutral organic donor**
topic Communications
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4227565/
https://www.ncbi.nlm.nih.gov/pubmed/24311295
http://dx.doi.org/10.1002/anie.201306543
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AT tuttletell metalfreereductivecleavageofcnandsnbondsbyphotoactivatedelectrontransferfromaneutralorganicdonor
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