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Regio- and Stereoselective Monoepoxidation of Dienes using Methyltrioxorhenium: Synthesis of Allylic Epoxides
[Image: see text] Methyltrioxorhenium (MTO) complexed with pyridine was shown to be a highly effective catalyst for the regioselective monoepoxidation of conjugated di- and trienes using 30% H(2)O(2) at or below room temperature. The resultant allylic epoxides, and the triols derived from them, are...
Autores principales: | , , , , , , , , |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
American Chemical
Society
2014
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Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4227570/ https://www.ncbi.nlm.nih.gov/pubmed/25321319 http://dx.doi.org/10.1021/jo501958d |