Isolation and Characterization of a Tetramethyliron(III) Ferrate: An Intermediate in the Reduction Pathway of Ferric Salts with MeMgBr

[Image: see text] While iron-catalyzed Kumada cross-coupling reactions with simple iron salts have been known since the early 1970s, the nature of the in situ-formed iron species remains elusive. Herein, we report the synthesis of the homoleptic tetralkyliron(III) ferrate complex [MgCl(THF)(5)][FeMe...

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Detalles Bibliográficos
Autores principales: Al-Afyouni, Malik H., Fillman, Kathlyn L., Brennessel, William W., Neidig, Michael L.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: American Chemical Society 2014
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4227835/
https://www.ncbi.nlm.nih.gov/pubmed/25333789
http://dx.doi.org/10.1021/ja5080757

Internet

https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4227835/
https://www.ncbi.nlm.nih.gov/pubmed/25333789
http://dx.doi.org/10.1021/ja5080757

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