Stable Silenolates and Brook-Type Silenes with Exocyclic Structures

[Image: see text] The first silenolates with exocyclic structures [(Me(3)Si)(2)Si(Si(2)Me(4))(2)SiC(R)O](−)K(+) (2a: R = 1-adamantyl; 2b: mesityl; 2c: o-tolyl) were synthesized by the reaction of the corresponding acylcyclohexasilanes 1a–c with KOtBu. NMR spectroscopy and single-crystal X-ray diffra...

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Detalles Bibliográficos
Autores principales: Haas, Michael, Fischer, Roland, Flock, Michaela, Mueller, Stefan, Rausch, Martin, Saf, Robert, Torvisco, Ana, Stueger, Harald
Formato: Online Artículo Texto
Lenguaje:English
Publicado: American Chemical Society 2014
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4228504/
https://www.ncbi.nlm.nih.gov/pubmed/25400314
http://dx.doi.org/10.1021/om500935r

Internet

https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4228504/
https://www.ncbi.nlm.nih.gov/pubmed/25400314
http://dx.doi.org/10.1021/om500935r

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