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Stable Silenolates and Brook-Type Silenes with Exocyclic Structures
[Image: see text] The first silenolates with exocyclic structures [(Me(3)Si)(2)Si(Si(2)Me(4))(2)SiC(R)O](−)K(+) (2a: R = 1-adamantyl; 2b: mesityl; 2c: o-tolyl) were synthesized by the reaction of the corresponding acylcyclohexasilanes 1a–c with KOtBu. NMR spectroscopy and single-crystal X-ray diffra...
| Autores principales: | , , , , , , , |
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| Formato: | Online Artículo Texto |
| Lenguaje: | English |
| Publicado: |
American Chemical Society
2014
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| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4228504/ https://www.ncbi.nlm.nih.gov/pubmed/25400314 http://dx.doi.org/10.1021/om500935r |