Unusually Efficient Pyridine Photodissociation from Ru(II) Complexes with Sterically Bulky Bidentate Ancillary Ligands

[Image: see text] The introduction of steric bulk to the bidentate ligand in [Ru(tpy)(bpy)(py)](2+) (1; tpy = 2,2′:2′,6″-terpyridine; bpy = 2,2′-bipyridine; py = pyridine) to provide [Ru(tpy)(Me(2)bpy)(py)](2+) (2; Me(2)bpy = 6,6′-dimethyl-2,2′-bipyridine) and [Ru(tpy)(biq)(py)](2+) (3; biq = 2,2′-b...

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Detalles Bibliográficos
Autores principales: Knoll, Jessica D., Albani, Bryan A., Durr, Christopher B., Turro, Claudia
Formato: Online Artículo Texto
Lenguaje:English
Publicado: American Chemical Society 2014
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4234441/
https://www.ncbi.nlm.nih.gov/pubmed/25027458
http://dx.doi.org/10.1021/jp5057732

Internet

https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4234441/
https://www.ncbi.nlm.nih.gov/pubmed/25027458
http://dx.doi.org/10.1021/jp5057732

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