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Unusually Efficient Pyridine Photodissociation from Ru(II) Complexes with Sterically Bulky Bidentate Ancillary Ligands
[Image: see text] The introduction of steric bulk to the bidentate ligand in [Ru(tpy)(bpy)(py)](2+) (1; tpy = 2,2′:2′,6″-terpyridine; bpy = 2,2′-bipyridine; py = pyridine) to provide [Ru(tpy)(Me(2)bpy)(py)](2+) (2; Me(2)bpy = 6,6′-dimethyl-2,2′-bipyridine) and [Ru(tpy)(biq)(py)](2+) (3; biq = 2,2′-b...
| Autores principales: | , , , |
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| Formato: | Online Artículo Texto |
| Lenguaje: | English |
| Publicado: |
American Chemical
Society
2014
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| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4234441/ https://www.ncbi.nlm.nih.gov/pubmed/25027458 http://dx.doi.org/10.1021/jp5057732 |