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Synthesis and Spectroscopic Characterization of High-Spin Mononuclear Iron(II) p-Semiquinonate Complexes

[Image: see text] Two mononuclear iron(II) p-semiquinonate (pSQ) complexes have been generated via one-electron reduction of precursor complexes containing a substituted 1,4-naphthoquinone ligand. Detailed spectroscopic and computational analysis confirmed the presence of a coordinated pSQ radical f...

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Detalles Bibliográficos
Autores principales: Baum, Amanda E., Park, Heaweon, Lindeman, Sergey V., Fiedler, Adam T.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: American Chemical Society 2014
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4254022/
https://www.ncbi.nlm.nih.gov/pubmed/25393154
http://dx.doi.org/10.1021/ic502564r