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Crystal structure of (2,11-di­aza­[3.3](2,6)pyridino­phane-κ (4) N,N′,N′′,N′′′)(1,6,7,12-tetra­aza­perylene-κ (2) N (1),N (12))ruthenium(II) bis­(hexa­fluorido­phosphate) aceto­nitrile 1.422-solvate

In the title compound, [Ru(C(14)H(16)N(4))(C(16)H(8)N(4))](PF(6))(2)·1.422CH(3)CN, discrete dimers of complex cations, [Ru(L–N(4)H(2))tape](2+) are formed {L–N(4)H(2) = 2,11-di­aza­[3.3](2,6)pyridino­phane; tape = 1,6,7,12-tetra­aza­perylene}, held together by π–π stacking inter­actions via the tape...

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Detalles Bibliográficos
Autores principales: Brietzke, Thomas, Rottke, Falko Otto, Kelling, Alexandra, Schilde, Uwe, Holdt, Hans-Jürgen
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2014
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4257199/
https://www.ncbi.nlm.nih.gov/pubmed/25484670
http://dx.doi.org/10.1107/S1600536814021060