Cargando…
Crystal structures of 3,6-diallyltetracyclo[6.3.0.0(4,11).0(5,9)]undeca-2,7-dione and 1,7-diallylpentacyclo[5.4.0.0(2,6). 0(3,10).0(5,9)]undecane-8,11-dione: allylated caged compounds
The title compounds, C(17)H(20)O(2) (1) and C(17)H(18)O(2) (2), are allylated caged compounds. In (1), the carbon atoms bearing the allyl groups are far apart [2.9417 (17) Å], hence the expected ring-closing metathesis (RCM) protocol failed to give a ring-closing product. When these carbon atoms ar...
Autores principales: | , , , |
---|---|
Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2014
|
Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4257271/ https://www.ncbi.nlm.nih.gov/pubmed/25484760 http://dx.doi.org/10.1107/S1600536814023149 |