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Crystal structures of 3,6-di­allyl­tetra­cyclo[6.3.0.0(4,11).0(5,9)]undeca-2,7-dione and 1,7-di­allyl­penta­cyclo­[5.4.0.0(2,6). 0(3,10).0(5,9)]undecane-8,11-dione: allyl­ated caged compounds

The title compounds, C(17)H(20)O(2) (1) and C(17)H(18)O(2) (2), are allyl­ated caged compounds. In (1), the carbon atoms bearing the allyl groups are far apart [2.9417 (17) Å], hence the expected ring-closing metathesis (RCM) protocol failed to give a ring-closing product. When these carbon atoms ar...

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Detalles Bibliográficos
Autores principales: Kotha, Sambasivarao, Seema, Vital, Deodhar, Deepak, Shaikh, Mobin
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2014
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4257271/
https://www.ncbi.nlm.nih.gov/pubmed/25484760
http://dx.doi.org/10.1107/S1600536814023149