Cargando…

Crystal structures of 3,6-diallyltetracyclo[6.3.0.0(4,11).0(5,9)]undeca-2,7-dione and 1,7-diallylpentacyclo[5.4.0.0(2,6). 0(3,10).0(5,9)]undecane-8,11-dione: allylated caged compounds

The title compounds, C(17)H(20)O(2) (1) and C(17)H(18)O(2) (2), are allylated caged compounds. In (1), the carbon atoms bearing the allyl groups are far apart [2.9417 (17) Å], hence the expected ring-closing metathesis (RCM) protocol failed to give a ring-closing product. When these carbon atoms ar...

Descripción completa

Detalles Bibliográficos
Autores principales:	Kotha, Sambasivarao, Seema, Vital, Deodhar, Deepak, Shaikh, Mobin
Formato:	Online Artículo Texto
Lenguaje:	English
Publicado:	International Union of Crystallography 2014
Materias:	Research Communications
Acceso en línea:	https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4257271/ https://www.ncbi.nlm.nih.gov/pubmed/25484760 http://dx.doi.org/10.1107/S1600536814023149

Ejemplares similares

1,7-Dimethylpentacyclo[5.4.0.0(2,6).0(3,10).0(5,9)]undecane-8,11-dione
por: Chakka, Sai Kumar, et al.
Publicado: (2010)

7-Methoxypentacyclo[5.4.0.0(2,6).0(3,10).0(5,9)]undecane-8,11-dione
por: Kotha, Sambasivarao, et al.
Publicado: (2020)

Crystal structure of the cage derivative pentacyclo[5.4.0.0(2,6).0(3,10).0(5,9)]undeca-8,11-dione ethylene dithioketal
por: Kotha, Sambasivarao, et al.
Publicado: (2014)

endo-11-(Dibenzylamino)tetracyclo[5.4.0.0(3,10).0(5,9)]undecane-8-one
por: Karpoormath, Rajshekhar, et al.
Publicado: (2011)

8-(Biphenyl-4-yl)-8-hydroxypentacyclo[5.4.0.0(2,6).0(3,10).0(5,9)]undecan-11-one ethylene ketal
por: Boyle, Grant A., et al.
Publicado: (2007)

N,N′-[(8-endo,11-endo-Dihydroxypentacyclo[5.4.0.0(2,6).0(3,10).0(5,9)]undecane-8,11-diyl)bis(methylenecarbonyl)]di-l-phenylalanine
por: Karpoormath, Rajshekhar, et al.
Publicado: (2010)

11-{[2-(3-Fluorophenyl)ethyl](methyl)amino}pentacyclo[5.4.0.0(2,6).0(3,10).0(5,9)]undecan-8-one
por: Banister, Samuel D., et al.
Publicado: (2010)

tert-Butyl N-[(11-exo-benzyloxycarbonyl-8-oxopentacyclo[5.4.0.0(2,6).0(3,10).0(5,9)]undecane-11-endo-yloxy)carbonylmethyl]carbamate
por: Karpoormath, Rajshekhar, et al.
Publicado: (2010)

Synthesis of New Pentacyclo[5.4.0.0(2,6).0(3,10).0(5,9)]undecane-8,11-dione (PCU) Cyanosilylated Derivatives Using Sulphated Zirconia and Hydrotalcite as Catalysts in Microwave-Assisted Reactions under Solvent Free Conditions
por: Guerra-Navarro, Nahí Adriana, et al.
Publicado: (2011)

Crystal structure of 6,6,12,12-tetrachlorotricyclo[8.2.0.0(4,7)]dodecane-5,11-dione
por: Turan Akın, Esra, et al.
Publicado: (2015)

3,22-Dioxa-11,14-diazapentacyclo[12.8.0.0(2,11).0(5,10).0(15,20)]docosa-5(10),6,8,15(20),16,18-hexaene-4,21-dione
por: Ren, Xiaolin, et al.
Publicado: (2013)

2,4-Dioxa-λ(6)-thiatetracyclo[5.3.1.1(5,9).0(1,5)]dodecane-3,3-dione
por: Ioannou, Savvas, et al.
Publicado: (2012)

4,10-Diformyl-2,6,8,12-tetranitro-2,4,6,8,10,12-hexaazatetracyclo[5.5.0.0(5,9).0(3,11)]dodecane
por: Chen, Huaxiong, et al.
Publicado: (2010)

10-Formyl-2,4,6,8,12-pentanitro-2,4,6,8,10,12-hexaazatetracyclo[5.5.0.0(3,11).0(5,9)]dodecane
por: Jin, Shaohua, et al.
Publicado: (2009)

Syntheses and crystal structures of the anhydride 4-oxatetracyclo[5.3.2.0(2,6).0(8,10)]dodec-11-ene-3,5-dione and the related imide 4-(4-bromophenyl)-4-azatetracyclo[5.3.2.0(2,6).0(8,10)]dodec-11-ene-3,5-dione
por: Hulsman, Andrew, et al.
Publicado: (2020)

10-Formyl-2,4,6,8,12-pentanitro-2,4,6,8,10,12-hexaazatetracyclo[5.5.0.0(5,9).0(3,11)]dodecane acetone solvate
por: Chen, Huaxiong, et al.
Publicado: (2010)

3,3,5,5-Tetramethyl-3,5-disila-4,10-dioxatetracyclo[5.5.1.0(2,6).0(8,12)]tridecane-9,11-dione
por: Sheng, Peng-Peng, et al.
Publicado: (2009)

Two‐Step Synthesis of Heptacyclo[6.6.0.0(2,6).0(3,13).0(4,11).0(5,9).0(10,14)] tetradecane from Norbornadiene: Mechanism of the Cage Assembly and Post‐synthetic Functionalization
por: Zieliński, Adam, et al.
Publicado: (2020)

Hybrid macrocycle formation and spiro annulation on cis-syn-cis-tricyclo[6.3.0.0(2,6)]undeca-3,11-dione and its congeners via ring-closing metathesis
por: Kotha, Sambasivarao, et al.
Publicado: (2015)

4,4-Dichlorotricyclo[5.4.0.0(3,5)]undeca-7,9,11-triene
por: Chen, Wan-Li, et al.
Publicado: (2008)

Benzyl 5-hydroxy-4-oxapentacyclo[5.4.1.0(2,6).0(3,10).0(8,11)]dodecane-3-carboxylate
por: Karpoormath, Rajshekhar, et al.
Publicado: (2011)

(±)-4,12,15,18,26-Pentahydroxy-13,17-dioxaheptacyclo[14.10.0.0(3,14).0(4,12).0(6,11).0(18,26).0(19,24)]hexacosa-1,3(14),6(11),7,9,15,19,21,23-nonaene-5,25-dione monohydrate
por: Mahmood, Khalid, et al.
Publicado: (2011)

(±)-4,12,15,18,26-Pentahydroxy-13,17-dioxaheptacyclo[14.10.0.0(3,14).0(4,12).0(6,11).0(18,26).0(19,24)]hexacosa-1,3(14),6(11),7,9,15,19,21,23-nonaene-5,25-dione methanol disolvate
por: Gil, Maayan, et al.
Publicado: (2014)

(1S,3S,8R,9S,11R)-10,10-Dibromo-3,7,7,11-tetramethyltetracyclo[6.5.0.0(1,3).0(9,11)]tridecane
por: Benharref, Ahmed, et al.
Publicado: (2013)

(1S,3S,8R,9S,11R)-10,10-Dichloro-3,7,7,11-tetramethyltetracyclo[6.5.0.0(1,3).0(9,11)]tridecane
por: Benharref, Ahmed, et al.
Publicado: (2013)

2,2-Dichloro-3,7,7,11-tetramethyl-10-azatetracyclo[6.5.0.0(1,3).0(9,11)]tridecane
por: Oukhrib, Abdelouahd, et al.
Publicado: (2013)

(1S,3R,8R,9S,11R)-2,2-Dibromo-10,10-dichloro-3,7,7,11-tetramethyltetracyclo[6.5.0.0(1,3).0(9,11)]tridecane
por: Ourhriss, Najia, et al.
Publicado: (2013)

(1S,3R,8R,9S,11R)-10,10-Dibromo-2,2-dichloro-3,7,7,11-tetramethyltetracyclo[6.5.0.0(1,3).0(9,11)]tridecane
por: Oukhrib, Abdelouahd, et al.
Publicado: (2013)

13-Hydroxy-4,16-dimethyl-4,16-diazapentacyclo[12.3.1.0(1,5).0(5,13).0(7,12)]octadeca-7(12),8,10-triene-6,18-dione
por: Suresh, J., et al.
Publicado: (2009)

16-Oxapentacyclo[6.6.5.0(1,18).0(2,7).0(9,14)]nonadeca-2,4,6,9,11,13,18-heptaen-15-one
por: Mathew, Eason M., et al.
Publicado: (2014)

19-Ferrocenyl-18-oxa-8,16-diazapentacyclo[8.6.3.0(1,10).0(2,7).0(12,16)]nonadeca-2(7),3,5-triene-9,17-dione
por: Gunasekaran, B., et al.
Publicado: (2010)

16-Isopropyl-5,9-dimethyltetracyclo[10.2.2.0(1,10).0(4,9)]hexadec-15-ene-5,14-dimethanol
por: Li, Jian, et al.
Publicado: (2011)

17-Hydroxy-1,8-dimethyl-17-azapentacyclo[6.6.5.0(2,7).0(9,14).0(15,19)]nonadeca-2,4,6,9(14),10,12-hexaene-16,18-dione
por: Miroslaw, Barbara, et al.
Publicado: (2012)

8-Phenyl-16-thiapentacyclo[6.6.5.0(1,18).0(2,7).0(9,14)]nonadeca-2,4,6,9,11,13,18-heptaene
por: Mathew, Eason M., et al.
Publicado: (2013)

Illustrator para Macintosh, versiones 5.0, 5.5 y 6.0 /
por: Weinmann, Elaine
Publicado: (1996)

10-Hydroxy-2-azapentacyclo[10.8.0.0(2,10).0(4,9).0(15,20)]icosa-1(12),4(9),5,7,13,15(20),16,18-octaene-3,11-dione
por: Hashemian, Saeedeh, et al.
Publicado: (2011)

Ethyl 4-(2-ethoxy-2-oxoethyl)-3-oxo-4,13-diazapentacyclo[11.8.0.0(2,11).0(5,10).0(14,19)]henicosa-1,5(10),6,8,11,14(19),15,17,20-nonaene-12-carboxylate
por: Meng, Qing-Hua, et al.
Publicado: (2013)

Crystal structure of 2,9-diphenyl-17λ(6)-thiatetracyclo[8.7.0.0(3,8).0(11,16)]heptadeca-1(10),2,4,6,8,11(16),12,14-octaene-17,17-dione
por: Gopinath, S., et al.
Publicado: (2014)

16-Isopropyl-5,9-dimethyltetracyclo[10.2.2.0(1,10).0(4,9)]hexadec-15-ene-5,14-dicarboxylic acid ethanol hemisolvate
por: Wang, Hong-Xiao, et al.
Publicado: (2009)

1,4,6,9-Tetra-tert-butyl-2,7-dioxatricyclo[6.3.0.0(3,6)]deca-3,8-diene
por: Sorensen, Ted S., et al.
Publicado: (2013)

Cannot write session to /tmp/vufind_sessions/sess_rsc3jlc84moou4j123vbtr9dr4