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Crystal structure of poly[(μ(3)-thio­cyanato-κ(3) N:S:S)(tri­methyl­phosphine sulfide-κS)copper(I)]

In the title compound, [Cu(NCS)(C(3)H(9)PS)](n), the thio­cyanate ions bind the Cu(I) atoms covalently, forming infinite –Cu—SCN—Cu– chains parallel to the a axis. Each Cu(I) atom is also coordinated to a tri­methyl­phosphine sulfide group via a Cu—S bond. Two crystallographically independent chains...

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Detalles Bibliográficos
Autor principal: Corfield, Peter W. R.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2014
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4257289/
https://www.ncbi.nlm.nih.gov/pubmed/25484723
http://dx.doi.org/10.1107/S1600536814021412