Crystal structure of a dinuclear Co(II) complex with bridging fluoride ligands: di-μ-fluorido-bis­{tris­[(6-methyl­pyridin-2-yl)meth­yl]amine}­dicobalt(II) bis­(tetra­fluorido­borate)

Reaction of Co(BF(4))(2)·6H(2)O with tris­[(6-methyl­pyridin-2-yl)meth­yl]amiine in methanol results in a fluoride abstraction from BF(4) (−), yielding the unexpected title compound, [Co(2)F(2)(C(21)H(24)N(4))(2)](BF(4))(2). The complex cation consists of two inversion-related [Co(C(21)H(24)N(4))](2...

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Detalles Bibliográficos
Autores principales: Inomata, Masataka, Suenaga, Yusaku
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2014
Materias:
Data Reports
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4257317/
https://www.ncbi.nlm.nih.gov/pubmed/25484774
http://dx.doi.org/10.1107/S1600536814021631

Internet

https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4257317/
https://www.ncbi.nlm.nih.gov/pubmed/25484774
http://dx.doi.org/10.1107/S1600536814021631

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