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Crystal structure of a dinuclear Co(II) complex with bridging fluoride ligands: di-μ-fluorido-bis{tris[(6-methylpyridin-2-yl)methyl]amine}dicobalt(II) bis(tetrafluoridoborate)

Reaction of Co(BF(4))(2)·6H(2)O with tris[(6-methylpyridin-2-yl)methyl]amiine in methanol results in a fluoride abstraction from BF(4) (−), yielding the unexpected title compound, [Co(2)F(2)(C(21)H(24)N(4))(2)](BF(4))(2). The complex cation consists of two inversion-related [Co(C(21)H(24)N(4))](2...

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Detalles Bibliográficos
Autores principales:	Inomata, Masataka, Suenaga, Yusaku
Formato:	Online Artículo Texto
Lenguaje:	English
Publicado:	International Union of Crystallography 2014
Materias:	Data Reports
Acceso en línea:	https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4257317/ https://www.ncbi.nlm.nih.gov/pubmed/25484774 http://dx.doi.org/10.1107/S1600536814021631

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