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Crystal structure of {2,2′-[ethyl­enebis(nitrilo­methanylyl­idene)]diphenolato-κ(4) O,N,N′,O′}oxidovanadium(IV) methanol monosolvate

Two independent mol­ecules of the title solvated complex, [V(C(16)H(14)N(2)O(2))O]·CH(3)OH, also known as [N,N′-bis­(salicyl­idene)ethyl­enedi­amine]­oxidovanadium(IV) or vanadyl salen, crystallize in the asymmetric unit. Each disordered methanol solvent mol­ecule [occupancy ratios 0.678 (4):0.322 (...

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Detalles Bibliográficos
Autores principales: Hsuan, Rachel E., Hughes, Jemma E., Miller, Thomas H., Shaikh, Nabila, Cunningham, Phoebe H. M., O’Connor, Alice E., Tidey, Jeremiah P., Blake, Alexander J.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2014
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4257326/
https://www.ncbi.nlm.nih.gov/pubmed/25484785
http://dx.doi.org/10.1107/S1600536814023332