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Crystal structure of tricarbonyl(N-diphenylphosphanyl-N,N′-diisopropyl-P-phenylphosphonous diamide-κ(2) P,P′)cobalt(I) tetracarbonylcobaltate(−I) toluene 0.25-solvate
The asymmetric unit of the title compound, [Co(C(24)H(30)N(2)P(2))(CO)(3)][Co(CO)(4)]·0.25C(7)H(8), consists of two crystallographically independent cations with similar conformations, two anions, and one-half of a toluene molecule disordered about an inversion centre. In the cations, a Co/P/N/P fo...
Autores principales: | , , |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2014
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4257381/ https://www.ncbi.nlm.nih.gov/pubmed/25552985 http://dx.doi.org/10.1107/S1600536814024908 |