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Crystal structure of tricarbon­yl(N-di­phenyl­phosphanyl-N,N′-diisopropyl-P-phenyl­phospho­nous di­amide-κ(2) P,P′)cobalt(I) tetra­carbonyl­cobaltate(−I) toluene 0.25-solvate

The asymmetric unit of the title compound, [Co(C(24)H(30)N(2)P(2))(CO)(3)][Co(CO)(4)]·0.25C(7)H(8), consists of two crystallographically independent cations with similar conformations, two anions, and one-half of a toluene mol­ecule disordered about an inversion centre. In the cations, a Co/P/N/P fo...

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Detalles Bibliográficos
Autores principales: Dura, Laura, Spannenberg, Anke, Beweries, Torsten
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2014
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4257381/
https://www.ncbi.nlm.nih.gov/pubmed/25552985
http://dx.doi.org/10.1107/S1600536814024908