Crystal structure of tricarbon­yl(N-di­phenyl­phosphanyl-N,N′-diisopropyl-P-phenyl­phospho­nous di­amide-κ(2) P,P′)cobalt(I) tetra­carbonyl­cobaltate(−I) toluene 0.25-solvate

The asymmetric unit of the title compound, [Co(C(24)H(30)N(2)P(2))(CO)(3)][Co(CO)(4)]·0.25C(7)H(8), consists of two crystallographically independent cations with similar conformations, two anions, and one-half of a toluene mol­ecule disordered about an inversion centre. In the cations, a Co/P/N/P fo...

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Detalles Bibliográficos
Autores principales: Dura, Laura, Spannenberg, Anke, Beweries, Torsten
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2014
Materias:
Research Communications
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4257381/
https://www.ncbi.nlm.nih.gov/pubmed/25552985
http://dx.doi.org/10.1107/S1600536814024908
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author Dura, Laura
Spannenberg, Anke
Beweries, Torsten
author_facet Dura, Laura
Spannenberg, Anke
Beweries, Torsten
author_sort Dura, Laura
collection PubMed
description The asymmetric unit of the title compound, [Co(C(24)H(30)N(2)P(2))(CO)(3)][Co(CO)(4)]·0.25C(7)H(8), consists of two crystallographically independent cations with similar conformations, two anions, and one-half of a toluene mol­ecule disordered about an inversion centre. In the cations, a Co/P/N/P four-membered slightly bent metallacycle is the key structural element. The pendant NH group is not coordinated to the Co(I) atom, which displays a distorted trigonal–bipyramidal coordination geometry. Weak inter­ionic hydrogen bonds are observed between the NH groups and a carbonyl group of the tetrahedral [Co(CO)(4)](−) anions.
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spelling pubmed-42573812014-12-31 Crystal structure of tricarbon­yl(N-di­phenyl­phosphanyl-N,N′-diisopropyl-P-phenyl­phospho­nous di­amide-κ(2) P,P′)cobalt(I) tetra­carbonyl­cobaltate(−I) toluene 0.25-solvate Dura, Laura Spannenberg, Anke Beweries, Torsten Acta Crystallogr Sect E Struct Rep Online Research Communications The asymmetric unit of the title compound, [Co(C(24)H(30)N(2)P(2))(CO)(3)][Co(CO)(4)]·0.25C(7)H(8), consists of two crystallographically independent cations with similar conformations, two anions, and one-half of a toluene mol­ecule disordered about an inversion centre. In the cations, a Co/P/N/P four-membered slightly bent metallacycle is the key structural element. The pendant NH group is not coordinated to the Co(I) atom, which displays a distorted trigonal–bipyramidal coordination geometry. Weak inter­ionic hydrogen bonds are observed between the NH groups and a carbonyl group of the tetrahedral [Co(CO)(4)](−) anions. International Union of Crystallography 2014-11-19 /pmc/articles/PMC4257381/ /pubmed/25552985 http://dx.doi.org/10.1107/S1600536814024908 Text en © Dura et al. 2014 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Research Communications
Dura, Laura
Spannenberg, Anke
Beweries, Torsten
Crystal structure of tricarbon­yl(N-di­phenyl­phosphanyl-N,N′-diisopropyl-P-phenyl­phospho­nous di­amide-κ(2) P,P′)cobalt(I) tetra­carbonyl­cobaltate(−I) toluene 0.25-solvate
title Crystal structure of tricarbon­yl(N-di­phenyl­phosphanyl-N,N′-diisopropyl-P-phenyl­phospho­nous di­amide-κ(2) P,P′)cobalt(I) tetra­carbonyl­cobaltate(−I) toluene 0.25-solvate
title_full Crystal structure of tricarbon­yl(N-di­phenyl­phosphanyl-N,N′-diisopropyl-P-phenyl­phospho­nous di­amide-κ(2) P,P′)cobalt(I) tetra­carbonyl­cobaltate(−I) toluene 0.25-solvate
title_fullStr Crystal structure of tricarbon­yl(N-di­phenyl­phosphanyl-N,N′-diisopropyl-P-phenyl­phospho­nous di­amide-κ(2) P,P′)cobalt(I) tetra­carbonyl­cobaltate(−I) toluene 0.25-solvate
title_full_unstemmed Crystal structure of tricarbon­yl(N-di­phenyl­phosphanyl-N,N′-diisopropyl-P-phenyl­phospho­nous di­amide-κ(2) P,P′)cobalt(I) tetra­carbonyl­cobaltate(−I) toluene 0.25-solvate
title_short Crystal structure of tricarbon­yl(N-di­phenyl­phosphanyl-N,N′-diisopropyl-P-phenyl­phospho­nous di­amide-κ(2) P,P′)cobalt(I) tetra­carbonyl­cobaltate(−I) toluene 0.25-solvate
title_sort crystal structure of tricarbon­yl(n-di­phenyl­phosphanyl-n,n′-diisopropyl-p-phenyl­phospho­nous di­amide-κ(2) p,p′)cobalt(i) tetra­carbonyl­cobaltate(−i) toluene 0.25-solvate
topic Research Communications
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4257381/
https://www.ncbi.nlm.nih.gov/pubmed/25552985
http://dx.doi.org/10.1107/S1600536814024908
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AT spannenberganke crystalstructureoftricarbonylndiphenylphosphanylnndiisopropylpphenylphosphonousdiamidek2ppcobaltitetracarbonylcobaltateitoluene025solvate
AT beweriestorsten crystalstructureoftricarbonylndiphenylphosphanylnndiisopropylpphenylphosphonousdiamidek2ppcobaltitetracarbonylcobaltateitoluene025solvate

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