Crystal structure of {3-[3,5-bis­(2,6-di­methyl­phen­yl)-1,2-phenyl­ene]-1-(2,6,2′′,6′′-tetra­methyl-1,1′:3′,1′′-ter­phen­yl-5′-yl)imidazol-2-yl­idene}chlorido­(η(6)-p-cymene)ruthenium(II) benzene disolvate

The title compound, [Ru(C(47)H(43)N(2))Cl(C(10)H(14))]·2C(6)H(6), crystallized with two independent mol­ecules of benzene. One of the N-aryl moieties of the N-heterocyclic carbene (NHC) ligand underwent cyclo­metallation to form a five-membered ruthenacycle. The complex has a three-legged piano-stoo...

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Detalles Bibliográficos
Autores principales: Sase, Shohei, Ikehara, Yuriko, Goto, Kei
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2014
Materias:
Data Reports
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4257382/
https://www.ncbi.nlm.nih.gov/pubmed/25553006
http://dx.doi.org/10.1107/S160053681402399X

Internet

https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4257382/
https://www.ncbi.nlm.nih.gov/pubmed/25553006
http://dx.doi.org/10.1107/S160053681402399X

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