Crystal structure of {3-[3,5-bis­(2,6-di­methyl­phen­yl)-1,2-phenyl­ene]-1-(2,6,2′′,6′′-tetra­methyl-1,1′:3′,1′′-ter­phen­yl-5′-yl)imidazol-2-yl­idene}chlorido­(η(6)-p-cymene)ruthenium(II) benzene disolvate

The title compound, [Ru(C(47)H(43)N(2))Cl(C(10)H(14))]·2C(6)H(6), crystallized with two independent mol­ecules of benzene. One of the N-aryl moieties of the N-heterocyclic carbene (NHC) ligand underwent cyclo­metallation to form a five-membered ruthenacycle. The complex has a three-legged piano-stoo...

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Detalles Bibliográficos
Autores principales: Sase, Shohei, Ikehara, Yuriko, Goto, Kei
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2014
Materias:
Data Reports
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4257382/
https://www.ncbi.nlm.nih.gov/pubmed/25553006
http://dx.doi.org/10.1107/S160053681402399X
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author Sase, Shohei
Ikehara, Yuriko
Goto, Kei
author_facet Sase, Shohei
Ikehara, Yuriko
Goto, Kei
author_sort Sase, Shohei
collection PubMed
description The title compound, [Ru(C(47)H(43)N(2))Cl(C(10)H(14))]·2C(6)H(6), crystallized with two independent mol­ecules of benzene. One of the N-aryl moieties of the N-heterocyclic carbene (NHC) ligand underwent cyclo­metallation to form a five-membered ruthenacycle. The complex has a three-legged piano-stool structure with two C atoms incorporated in the five-membered ruthenacycle and a Cl atom as legs. The ruthenacycle is essentially coplanar with the imidazole ring of the NHC ligand, making a dihedral angle of 0.85 (8)°.
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spelling pubmed-42573822014-12-31 Crystal structure of {3-[3,5-bis­(2,6-di­methyl­phen­yl)-1,2-phenyl­ene]-1-(2,6,2′′,6′′-tetra­methyl-1,1′:3′,1′′-ter­phen­yl-5′-yl)imidazol-2-yl­idene}chlorido­(η(6)-p-cymene)ruthenium(II) benzene disolvate Sase, Shohei Ikehara, Yuriko Goto, Kei Acta Crystallogr Sect E Struct Rep Online Data Reports The title compound, [Ru(C(47)H(43)N(2))Cl(C(10)H(14))]·2C(6)H(6), crystallized with two independent mol­ecules of benzene. One of the N-aryl moieties of the N-heterocyclic carbene (NHC) ligand underwent cyclo­metallation to form a five-membered ruthenacycle. The complex has a three-legged piano-stool structure with two C atoms incorporated in the five-membered ruthenacycle and a Cl atom as legs. The ruthenacycle is essentially coplanar with the imidazole ring of the NHC ligand, making a dihedral angle of 0.85 (8)°. International Union of Crystallography 2014-11-08 /pmc/articles/PMC4257382/ /pubmed/25553006 http://dx.doi.org/10.1107/S160053681402399X Text en © Sase et al. 2014 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Data Reports
Sase, Shohei
Ikehara, Yuriko
Goto, Kei
Crystal structure of {3-[3,5-bis­(2,6-di­methyl­phen­yl)-1,2-phenyl­ene]-1-(2,6,2′′,6′′-tetra­methyl-1,1′:3′,1′′-ter­phen­yl-5′-yl)imidazol-2-yl­idene}chlorido­(η(6)-p-cymene)ruthenium(II) benzene disolvate
title Crystal structure of {3-[3,5-bis­(2,6-di­methyl­phen­yl)-1,2-phenyl­ene]-1-(2,6,2′′,6′′-tetra­methyl-1,1′:3′,1′′-ter­phen­yl-5′-yl)imidazol-2-yl­idene}chlorido­(η(6)-p-cymene)ruthenium(II) benzene disolvate
title_full Crystal structure of {3-[3,5-bis­(2,6-di­methyl­phen­yl)-1,2-phenyl­ene]-1-(2,6,2′′,6′′-tetra­methyl-1,1′:3′,1′′-ter­phen­yl-5′-yl)imidazol-2-yl­idene}chlorido­(η(6)-p-cymene)ruthenium(II) benzene disolvate
title_fullStr Crystal structure of {3-[3,5-bis­(2,6-di­methyl­phen­yl)-1,2-phenyl­ene]-1-(2,6,2′′,6′′-tetra­methyl-1,1′:3′,1′′-ter­phen­yl-5′-yl)imidazol-2-yl­idene}chlorido­(η(6)-p-cymene)ruthenium(II) benzene disolvate
title_full_unstemmed Crystal structure of {3-[3,5-bis­(2,6-di­methyl­phen­yl)-1,2-phenyl­ene]-1-(2,6,2′′,6′′-tetra­methyl-1,1′:3′,1′′-ter­phen­yl-5′-yl)imidazol-2-yl­idene}chlorido­(η(6)-p-cymene)ruthenium(II) benzene disolvate
title_short Crystal structure of {3-[3,5-bis­(2,6-di­methyl­phen­yl)-1,2-phenyl­ene]-1-(2,6,2′′,6′′-tetra­methyl-1,1′:3′,1′′-ter­phen­yl-5′-yl)imidazol-2-yl­idene}chlorido­(η(6)-p-cymene)ruthenium(II) benzene disolvate
title_sort crystal structure of {3-[3,5-bis­(2,6-di­methyl­phen­yl)-1,2-phenyl­ene]-1-(2,6,2′′,6′′-tetra­methyl-1,1′:3′,1′′-ter­phen­yl-5′-yl)imidazol-2-yl­idene}chlorido­(η(6)-p-cymene)ruthenium(ii) benzene disolvate
topic Data Reports
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4257382/
https://www.ncbi.nlm.nih.gov/pubmed/25553006
http://dx.doi.org/10.1107/S160053681402399X
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AT ikeharayuriko crystalstructureof335bis26dimethylphenyl12phenylene12626tetramethyl1131terphenyl5ylimidazol2ylidenechloridoē6pcymenerutheniumiibenzenedisolvate
AT gotokei crystalstructureof335bis26dimethylphenyl12phenylene12626tetramethyl1131terphenyl5ylimidazol2ylidenechloridoē6pcymenerutheniumiibenzenedisolvate

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