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Crystal structure of di-μ-iodido-bis­[(dimethyl sulfoxide-κO)(tri­phenyl­phosphane-κP)copper(I)]

The centrosymmetric dinuclear title compound, [Cu(2)I(2)(C(2)H(6)OS)(2)(C(18)H(15)P)(2)], represents the first example of a CuI complex ligated by an O-bound dimethyl sulfoxide ligand. In the crystal, the two tetrahedrally coordinated Cu(I) atoms are bridged by two μ(2)-iodido ligands in an almost s...

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Detalles Bibliográficos
Autores principales: Kinghat, Rodolphe, Knorr, Michael, Rousselin, Yoann, Kubicki, Marek M.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2014
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4257398/
https://www.ncbi.nlm.nih.gov/pubmed/25552989
http://dx.doi.org/10.1107/S1600536814025203