Crystal structure of di-μ-iodido-bis­[(dimethyl sulfoxide-κO)(tri­phenyl­phosphane-κP)copper(I)]

The centrosymmetric dinuclear title compound, [Cu(2)I(2)(C(2)H(6)OS)(2)(C(18)H(15)P)(2)], represents the first example of a CuI complex ligated by an O-bound dimethyl sulfoxide ligand. In the crystal, the two tetrahedrally coordinated Cu(I) atoms are bridged by two μ(2)-iodido ligands in an almost s...

Descripción completa

Detalles Bibliográficos
Autores principales: Kinghat, Rodolphe, Knorr, Michael, Rousselin, Yoann, Kubicki, Marek M.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2014
Materias:
Research Communications
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4257398/
https://www.ncbi.nlm.nih.gov/pubmed/25552989
http://dx.doi.org/10.1107/S1600536814025203
_version_ 1782347742344904704
author Kinghat, Rodolphe
Knorr, Michael
Rousselin, Yoann
Kubicki, Marek M.
author_facet Kinghat, Rodolphe
Knorr, Michael
Rousselin, Yoann
Kubicki, Marek M.
author_sort Kinghat, Rodolphe
collection PubMed
description The centrosymmetric dinuclear title compound, [Cu(2)I(2)(C(2)H(6)OS)(2)(C(18)H(15)P)(2)], represents the first example of a CuI complex ligated by an O-bound dimethyl sulfoxide ligand. In the crystal, the two tetrahedrally coordinated Cu(I) atoms are bridged by two μ(2)-iodido ligands in an almost symmetrical rhomboid geometry. The loose Cu⋯Cu contact of 2.9874 (8) Å is longer than the sum of the van der Waals radii of two Cu atoms (2.8 Å), excluding a significant cupriophilic inter­action in the actual dimer. C—H⋯O and C—H⋯I hydrogen bonding interactions as well as C—H⋯π(aryl) interactions stabilize the three-dimensional supramolecular network.
format Online
Article
Text
id pubmed-4257398
institution National Center for Biotechnology Information
language English
publishDate 2014
publisher International Union of Crystallography
record_format MEDLINE/PubMed
spelling pubmed-42573982014-12-31 Crystal structure of di-μ-iodido-bis­[(dimethyl sulfoxide-κO)(tri­phenyl­phosphane-κP)copper(I)] Kinghat, Rodolphe Knorr, Michael Rousselin, Yoann Kubicki, Marek M. Acta Crystallogr Sect E Struct Rep Online Research Communications The centrosymmetric dinuclear title compound, [Cu(2)I(2)(C(2)H(6)OS)(2)(C(18)H(15)P)(2)], represents the first example of a CuI complex ligated by an O-bound dimethyl sulfoxide ligand. In the crystal, the two tetrahedrally coordinated Cu(I) atoms are bridged by two μ(2)-iodido ligands in an almost symmetrical rhomboid geometry. The loose Cu⋯Cu contact of 2.9874 (8) Å is longer than the sum of the van der Waals radii of two Cu atoms (2.8 Å), excluding a significant cupriophilic inter­action in the actual dimer. C—H⋯O and C—H⋯I hydrogen bonding interactions as well as C—H⋯π(aryl) interactions stabilize the three-dimensional supramolecular network. International Union of Crystallography 2014-11-21 /pmc/articles/PMC4257398/ /pubmed/25552989 http://dx.doi.org/10.1107/S1600536814025203 Text en © Kinghat et al. 2014 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Research Communications
Kinghat, Rodolphe
Knorr, Michael
Rousselin, Yoann
Kubicki, Marek M.
Crystal structure of di-μ-iodido-bis­[(dimethyl sulfoxide-κO)(tri­phenyl­phosphane-κP)copper(I)]
title Crystal structure of di-μ-iodido-bis­[(dimethyl sulfoxide-κO)(tri­phenyl­phosphane-κP)copper(I)]
title_full Crystal structure of di-μ-iodido-bis­[(dimethyl sulfoxide-κO)(tri­phenyl­phosphane-κP)copper(I)]
title_fullStr Crystal structure of di-μ-iodido-bis­[(dimethyl sulfoxide-κO)(tri­phenyl­phosphane-κP)copper(I)]
title_full_unstemmed Crystal structure of di-μ-iodido-bis­[(dimethyl sulfoxide-κO)(tri­phenyl­phosphane-κP)copper(I)]
title_short Crystal structure of di-μ-iodido-bis­[(dimethyl sulfoxide-κO)(tri­phenyl­phosphane-κP)copper(I)]
title_sort crystal structure of di-μ-iodido-bis­[(dimethyl sulfoxide-κo)(tri­phenyl­phosphane-κp)copper(i)]
topic Research Communications
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4257398/
https://www.ncbi.nlm.nih.gov/pubmed/25552989
http://dx.doi.org/10.1107/S1600536814025203
work_keys_str_mv AT kinghatrodolphe crystalstructureofdimiodidobisdimethylsulfoxidekotriphenylphosphanekpcopperi
AT knorrmichael crystalstructureofdimiodidobisdimethylsulfoxidekotriphenylphosphanekpcopperi
AT rousselinyoann crystalstructureofdimiodidobisdimethylsulfoxidekotriphenylphosphanekpcopperi
AT kubickimarekm crystalstructureofdimiodidobisdimethylsulfoxidekotriphenylphosphanekpcopperi

Ejemplares similares