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Unexpected formation and crystal structure of tetra­kis­(1H-pyrazole-κN (2))­palladium(II) dichloride

The title salt, [Pd(C(3)H(4)N(2))(4)]Cl(2), was obtained unexpectedly by the reaction of palladium(II) dichloride with equimolar amounts of 1-chloro-1-nitro-2,2,2-tris­(pyrazol­yl)ethane in methanol solution. The Pd(2+) cation is located on an inversion centre and has a square-planar coordination sp...

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Detalles Bibliográficos
Autores principales: Wagner, Thomas, Christiansen, Nena, Hrib, Cristian G., Kaufmann, Dieter E., Edelmann, Frank T.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2014
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4257448/
https://www.ncbi.nlm.nih.gov/pubmed/25552973
http://dx.doi.org/10.1107/S160053681402460X