Crystal structure of (1S,2R,6R,7R,8S,12S)-4,10,17-triphenyl-15-thia-4,10-diaza­penta­cyclo[5.5.5.0(1,16).0(2,6).0(8,12)]hepta­deca-13,16-diene-3,5,9,11-tetrone p-xylene hemisolvate

The title tetrone compound, C(32)H(22)N(2)O(4)S· 0.5C(8)H(10), is the major product (50% yield) of an attempted Diels–Alder reaction of 2-(α-styr­yl)thio­phene with N-phenyl­male­imide (2 equivalents) in toluene. Recrystallization of the resulting powder from p-xylene gave the title hemisolvate; the...

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Detalles Bibliográficos
Autores principales: Noland, Wayland E., Kroll, Neil J., Huisenga, Matthew P., Yue, Ruixian A., Lang, Simon B., Klein, Nathan D., Tritch, Kenneth J.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2014
Materias:
Research Communications
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4257460/
https://www.ncbi.nlm.nih.gov/pubmed/25552990
http://dx.doi.org/10.1107/S1600536814025094

Internet

https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4257460/
https://www.ncbi.nlm.nih.gov/pubmed/25552990
http://dx.doi.org/10.1107/S1600536814025094

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