Crystal Structures of the Carborane Dianions [1,4-(PhCB(10)H(10)C)(2)C(6)H(4)](2−) and [1,4-(PhCB(10)H(10)C)(2)C(6)F(4)](2−) and the Stabilizing Role of the para-Phenylene Unit on 2 n+3 Skeletal Electron Clusters**

While carboranes with 2 n+2 and 2 n+4 (n=number of skeletal atoms) skeletal electrons (SE) are widely known, little has been reported on carboranes with odd SE numbers. Electrochemical measurements on two-cage assemblies, where two C-phenyl-ortho-carboranyl groups are linked by a para-phenylene or a...

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Detalles Bibliográficos
Autores principales: Kahlert, Jan, Stammler, Hans-Georg, Neumann, Beate, Harder, Rachel A, Weber, Lothar, Fox, Mark A
Formato: Online Artículo Texto
Lenguaje:English
Publicado: WILEY-VCH Verlag 2014
Materias:
Communications
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4257503/
https://www.ncbi.nlm.nih.gov/pubmed/24574170
http://dx.doi.org/10.1002/anie.201310718

Internet

https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4257503/
https://www.ncbi.nlm.nih.gov/pubmed/24574170
http://dx.doi.org/10.1002/anie.201310718

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