Cargando…
A Catalytic Borylation/Dehalogenation Route to o-Fluoro Arylboronates
[Image: see text] A two-step Ir-catalyzed borylation/Pd-catalyzed dehalogenation sequence allows for the net synthesis of fluoroarenes where the boronic ester is ortho to fluorine. Key elements of this approach include the use of a halogen para to the fluorine to block meta Ir-catalyzed borylation a...
Autores principales: | , , , , |
---|---|
Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
American
Chemical Society
2014
|
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4260632/ https://www.ncbi.nlm.nih.gov/pubmed/25418716 http://dx.doi.org/10.1021/ol5028738 |