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Mechanistic studies on covalent assemblies of metal-mediated hemi-aminal ethers

The use of reversible covalent bonding in a four-component assembly incorporating chiral alcohols was recently reported to give a method for determining the enantiomeric excess of the alcohols via CD spectroscopy. Experiments that probe the mechanism of this assembly, which consists of 2-formylpyrid...

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Detalles Bibliográficos
Autores principales: Jo, Hyun Hwa, Edupuganti, Ramakrishna, You, Lei, Dalby, Kevin N., Anslyn, Eric V.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: Royal Society of Chemistry 2015
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4267293/
https://www.ncbi.nlm.nih.gov/pubmed/25530834
http://dx.doi.org/10.1039/c4sc02495h