Preparation of Macrocyclic Z-Enoates and (E,Z)- or (Z,E)-Dienoates through Catalytic Stereoselective Ring-Closing Metathesis

[Image: see text] The first examples of catalyst-controlled stereoselective macrocyclic ring-closing metathesis reactions that generate Z-enoates as well as (E,Z)- or (Z,E)-dienoates are disclosed. Reactions promoted by 3.0–10 mol % of a Mo-based monoaryloxide pyrrolide complex proceed to completion...

Descripción completa

Detalles Bibliográficos
Autores principales: Zhang, Hanmo, Yu, Elsie C., Torker, Sebastian, Schrock, Richard R., Hoveyda, Amir H.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: American Chemical Society 2014
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4270125/
https://www.ncbi.nlm.nih.gov/pubmed/25402822
http://dx.doi.org/10.1021/ja510768c

Internet

https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4270125/
https://www.ncbi.nlm.nih.gov/pubmed/25402822
http://dx.doi.org/10.1021/ja510768c

Ejemplares similares