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Design and synthesis of novel bis-annulated caged polycycles via ring-closing metathesis: pushpakenediol

Intricate caged molecular frameworks are assembled by an atom economical process via a Diels–Alder (DA) reaction, a Claisen rearrangement, a ring-closing metathesis (RCM) and an alkenyl Grignard addition. The introduction of olefinic moieties in the pentacycloundecane (PCUD) framework at appropriate...

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Detalles Bibliográficos
Autores principales: Kotha, Sambasivarao, Dipak, Mirtunjay Kumar
Formato: Online Artículo Texto
Lenguaje:English
Publicado: Beilstein-Institut 2014
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4273234/
https://www.ncbi.nlm.nih.gov/pubmed/25550729
http://dx.doi.org/10.3762/bjoc.10.280