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Design and synthesis of novel bis-annulated caged polycycles via ring-closing metathesis: pushpakenediol
Intricate caged molecular frameworks are assembled by an atom economical process via a Diels–Alder (DA) reaction, a Claisen rearrangement, a ring-closing metathesis (RCM) and an alkenyl Grignard addition. The introduction of olefinic moieties in the pentacycloundecane (PCUD) framework at appropriate...
Autores principales: | , |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
Beilstein-Institut
2014
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4273234/ https://www.ncbi.nlm.nih.gov/pubmed/25550729 http://dx.doi.org/10.3762/bjoc.10.280 |