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Synthesis of an organic-soluble π-conjugated [3]rotaxane via rotation of glucopyranose units in permethylated β-cyclodextrin

We synthesized symmetrically insulated oligo(para-phenylene) and oligothiophene with a pseudo-linked [3]rotaxane structure by full rotation of glucopyranose units via a flipping (tumbling) mechanism in the π-conjugated guest having two permethylated β-cyclodextrin units at both ends. We also succeed...

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Detalles Bibliográficos
Autores principales: Terao, Jun, Konoshima, Yohei, Matono, Akitoshi, Masai, Hiroshi, Fujihara, Tetsuaki, Tsuji, Yasushi
Formato: Online Artículo Texto
Lenguaje:English
Publicado: Beilstein-Institut 2014
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4273295/
https://www.ncbi.nlm.nih.gov/pubmed/25550746
http://dx.doi.org/10.3762/bjoc.10.297