Silanetriols as Powerful Starting Materials for Selective Condensation to Bulky POSS Cages

[Image: see text] Controlled condensation reactions of tertiary silanetriols CH(3)(CH(2))(n)(CH(3))(2)CSi(OH)(3) (1b–f; n = 1–5) in the presence of trifluoroacetic acid and the hydrolysis of CH(3)(CH(2))(6)(CH(3))(2)CSiCl(3) (3) lead to the selective formation of the corresponding disiloxane tetrols...

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Detalles Bibliográficos
Autores principales: Hurkes, Natascha, Bruhn, Clemens, Belaj, Ferdinand, Pietschnig, Rudolf
Formato: Online Artículo Texto
Lenguaje:English
Publicado: American Chemical Society 2014
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4276717/
https://www.ncbi.nlm.nih.gov/pubmed/25550679
http://dx.doi.org/10.1021/om5010918

Internet

https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4276717/
https://www.ncbi.nlm.nih.gov/pubmed/25550679
http://dx.doi.org/10.1021/om5010918

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