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Silanetriols as Powerful Starting Materials for Selective Condensation to Bulky POSS Cages
[Image: see text] Controlled condensation reactions of tertiary silanetriols CH(3)(CH(2))(n)(CH(3))(2)CSi(OH)(3) (1b–f; n = 1–5) in the presence of trifluoroacetic acid and the hydrolysis of CH(3)(CH(2))(6)(CH(3))(2)CSiCl(3) (3) lead to the selective formation of the corresponding disiloxane tetrols...
| Autores principales: | , , , |
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| Formato: | Online Artículo Texto |
| Lenguaje: | English |
| Publicado: |
American
Chemical Society
2014
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| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4276717/ https://www.ncbi.nlm.nih.gov/pubmed/25550679 http://dx.doi.org/10.1021/om5010918 |