Enantioselective Selenocyclization via Dynamic Kinetic Resolution of Seleniranium Ions by Hydrogen-Bond Donor Catalysts

[Image: see text] Highly enantioselective selenocyclization reactions are promoted by the combination of a new chiral squaramide catalyst, a mineral acid, and an achiral Lewis base. Mechanistic studies reveal that the enantioselectivity originates from the dynamic kinetic resolution of seleniranium...

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Detalles Bibliográficos
Autores principales: Zhang, Hu, Lin, Song, Jacobsen, Eric N.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: American Chemical Society 2014
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4277748/
https://www.ncbi.nlm.nih.gov/pubmed/25380129
http://dx.doi.org/10.1021/ja510113s

Internet

https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4277748/
https://www.ncbi.nlm.nih.gov/pubmed/25380129
http://dx.doi.org/10.1021/ja510113s

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