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Nickel-Catalyzed Negishi Arylations of Propargylic Bromides: A Mechanistic Investigation
[Image: see text] Although nickel-catalyzed stereoconvergent couplings of racemic alkyl electrophiles are emerging as a powerful tool in organic chemistry, to date there have been no systematic mechanistic studies of such processes. Herein, we examine the pathway for enantioselective Negishi arylati...
Autores principales: | , |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
American Chemical
Society
2014
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Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4277758/ https://www.ncbi.nlm.nih.gov/pubmed/25402209 http://dx.doi.org/10.1021/ja508718m |